Gwyneth Paltrow
Long before she founded Goop, Paltrow was a budding actress in the '90s (with a Hollywood pedigree) who starred in made-for-TV movies like Cruel Doubt (pictured here) before she got her part in Se7en. While Se7en didn't end well for her character (spoilers for those who don't know what was inside the box), it launched her film career and she went on to do Moonlight and Valentino, Emma, Sliding Doors, Shakespeare in Love, Iron Man, and so many more films before launching her lifestyle brand.