Hollywood's most adorable A-list duos hit the red carpet looking very stylish ... and smitten.
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1 of 13
Natalie Portman & Benjamin Millepied
The pregnant Black Swan star chatted with her fiancé — who also choreographed the nominated film and played her dance partner — who sported matching bright crimson accents.
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2 of 13
Brad Pitt & Angelina Jolie
The famous couple oozed sexiness on the red carpet — he in cool shades and a classic tux, and she in a drop-dead gorgeous emerald sequined Versace.
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3 of 13
Heidi Klum & Seal
The Project Runway host and her singer hubby dressed to match in seventies-style digs, with Seal sporting a leather suit and Heidi rocking stacked heels, beachy hair, and a Pucci-esque scarf dress.
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4 of 13
Jennifer Lopez & Marc Anthony
The happy couple were all smiles as they traipsed down the red carpet together.
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5 of 13
Jennifer Love Hewitt & Alex Beh
The actress and her new actor/producer beau sported similarly mussed hairdos along with big smiles.
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6 of 13
Jon Hamm & Jennifer Westfeldt
The Mad Men star and his longtime girlfriend walked the carpet arm-in-arm.
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7 of 13
Kevin Bacon & Kyra Sedgwick
The Closer star, who was nominated for Best Actress in a TV Series, stayed close to her hubby throughout the pre-show.
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8 of 13
Jane Lynch & Lara Embry
The hilarious Glee star and her partner made for an elegant pair in flowing, pleated gowns.
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9 of 13
Megan Fox & Brian Austin Green
The brunette bombshell and her proud hubby both dressed head to toe in smoking-hot Armani.
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10 of 13
Catherine Zeta-Jones & Michael Douglas
The beautiful actress and her now-cancer-free husband appeared on the carpet looking very “Old Hollywood” glamorous.
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11 of 13
Nicole Kidman & Keith Urban
The Oscar-winning actress — now nominated for her role in Rabbit Hole — and her country singer husband looked radiant in matching Prada.
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12 of 13
Ricky Gervais & Jane Fallon
The cheeky host and his longtime girlfriend smile their way down the red carpet.
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13 of 13
Robert Downey, Jr. & Susan Downey
The Iron Man actor and his producer wife embodied simple elegance.
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